There have been a number of threads on Trapshooter.com regarding both barrel bursts, and what have appeared to be catastrophic explosions destroying entire guns. Some posts have been illuminating but many simply a repetition of the unknowable and unsubstantiated

Anyway, here are 3 for those interested:
Shotgun Blowups
http://www.trapshooters.com/threads/shotgun-blowups.244114/ Smokeless Powder DDT (I am a believer therein but THIS EVENT WAS
NOT DDT)
http://www.trapshooters.com/threads/smokeless-powder-ddt.245629/Base wad obstruction
http://www.trapshooters.com/threads/base-wad-in-barrel.220936/ Bruce Bowen's experiment is referenced, and he was using a H&R single barrel. His failure to burst the barrel, and Sherman Bell's effort published in
DGJ show the intrinsic safety margin of UNOBSTRUCTED barrels
DGJ, Vol 18, Issue 1, Spring 2007 -
1. Destructive testing on a Damascus barrel with thinned walls; calculated by O.D. - I.D., not measured
2. Destructive testing using various obstructions, including a 20g shell
3. Destructive testing using a shell loaded with 3 1/4 Drams by volume or 56 grains of Unique (similar to “Infallible”) with 1 1/4 oz. shot.
"where the empty cartridges went"
Just wanted clarification that BOTH cartridge
s were empty.
I believe the initial event was obstruction in the lower barrel, and at the moment of the burst the shooter involuntarily pulled the trigger firing the top barrel. All this happened in milliseconds, so it's impossible to know. The (presumed) detonation destructions and obstructional bursts that I've reviewed, when both barrels were loaded, have not been associated with the shell in the other barrel firing.
The recoil from the initial burst (unless a double powder handload) is not greater, so it would seem unlikely that the sear would release the top barrel hammer.
One would expect that the shooter would have noticed a shell looking like this Winchester Universal

And can see how the deformed wad could certainly obstruct the barrel

BTW: A study by the Royal Military College of Science, sponsored by the Birmingham Proof House and the British Association for Shooting and Conservation, showed that an obstruction by 2 fibre wads (total weight of 4 grams) was sufficient to bulge or burst a 12 gauge barrel shooting a 28 gram (slightly less than 1 ounce) load. Peak pressure occurred 22mm (.866”) past the leading edge of the obstruction.